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11.
We investigated Au catalysts supported on TiO2, Fe2O3, and ZnO for their preferential oxidation of CO in a H2-rich atmosphere. Both full conversion and selectivity were achieved over Au/Fe2O3 and Au/ZnO around room temperature, but at higher temperatures the CO conversion was suppressed due to competition between CO and H2. 相似文献
12.
Resistance microwelding of fine crossed nickel wires is of increasing industrial importance for electrical connections in
downsized electronic and medical devices, but the understanding of the process is very limited. A study has, therefore, been
performed to clarify the basic joining mechanisms, in which the effects of main process parameters (welding current and force
and weld time) were investigated by detailed mechanical testing and metallurgical examinations. A bonding mechanism with main
process stages (wire cold collapse, surface melting, molten-phase squeeze-out and, solid-state bonding) was proposed. A new
technique has also been developed to optimize the process by initiating the welding current well before the electrode force
has reached its full nominal value. 相似文献
13.
Poly(L-ornithine)s having various azo-contents in the side chains were synthesized by the water-soluble carbodiimide procedure. The photochemical properties of the polypeptides poly[Nδ-p-(phenylazo)benzoyl-L-ornithine] (PPABLO) containing 3–77 mol% azobenzene were investigated by absorption and circular dichroism spectroscopy in hexafluoro-2-propanol (HFIP) or water, and in HFIP-water or methanol-water solvent mixtures. The photochromism of the dichroic bands of the PPABLOs containing 20–77 mol% azobenzene in the visible and ultraviolet wavelength regions was found to be mostly reversible as a function of irradiation time at different wavelengths due to the photostationary state (above 80% trans-cis photoisomerization) of the azo aromatic moieties. The PPABLO containing 3.2 mol% azobenzene in water exhibited conformational changes from random coil to helix by the addition of methanol or sodium dodecyl sulphate (SDS). The photo-induced conformational change was observed in HFIP-water-SDS solvent mixtures, while no conformational change was seen in water and HFIP-water solvent mixtures. 相似文献
14.
S Fukumoto M Suzawa Y Takeuchi Y Kodama K Nakayama E Ogata T Matsumoto T Fujita 《Canadian Metallurgical Quarterly》1996,81(7):2554-2558
15.
R Fukuda XT Nguyen N Ishimura S Ishihara A Chowdhury N Kohge S Akagi M Watanabe S Fukumoto 《Canadian Metallurgical Quarterly》1995,172(5):1191-1197
Hepatitis B virus (HBV) carriers with antibody to hepatitis e antigen comprise asymptomatic carriers (ASCs), who have low replication levels of HBV, and patients with chronic active hepatitis (CAH), who have high levels of viral replication. To investigate whether defects in the X protein might be responsible for this difference in the level of viral replication, nucleotide sequences of X and precore gene regions in serum HBV were analyzed in 19 ASCs and 9 CAH patients. All patients had a point mutation creating a stop codon in the precore region. Seventeen ASCs (87.3%) had identical mutations consisting of 4 noncontiguous 1-bp deletions or an 8-bp deletion, both of which truncate the normal X protein, whereas no CAH patient had an X gene mutation (P < .001). Thus, deletion of the X protein might be responsible for the low levels of viral replication in ASCs. 相似文献
16.
Masaaki Miyamoto Hiroyuki Koike Toshio Sada Yasuteru Ijima Junichiro Fukushige Norio Nakamura 《Lipids》1991,26(12):1316-1319
Platelet-activating factor (PAF) is a potent inflammatory mediator which is released by various inflammatory cells and produced
by certain tissues, including the kidney. PAF has been shown to increase glomerular permeability to protein and to decrease
glomerular filtration rate (GFR) by contracting mesangium. On the basis of these observations, it has been suspected that
PAF may play a role as mediator of glomerular damage in glomerular nephritis. To examine this possibility, we studied the
effects of a specific PAF antagonist, R-75,317, on the development of an experimental model of anti-glomerular basement membrane
(anti-GBM) glomerulonephritis. Glomerulonephritis was initiated by injecting rabbit anti-rat GBM serum into rats. Proteinuria
gradually developed after serum injection, plateaued at week 2, and remained at the high level of week 2 throughout the experimental
period (6 wk). Chronic treatment with R-75,317 (10 mg/kg/day i.p.) tended to delay the onset of proteinuria and significantly
accelerated the recovery phase. Creatinine clearance (Ccr) fell to 40% at week 3. R-75,317 treatment completely prevented
this decline of Ccr. Histological changes in this model (glomerular hypertrophy, proliferation of mesangial matrix and interstitial
fibrosis) were also ameliorated by the R-75,317 treatment. The results suggest that PAF may play a role in the development
of glomerulonephritis and that PAF antagonists could be used in the treatment of human renal disease.
Based on a paper presented at the Third International Conference on Platelet-Activating Factor and Structurally Related Alkyl
Ether Lipids, May 1989. 相似文献
17.
Tohru Morii Hiroyuki Hamada Muriel Desaeger Akihiko Gotoh Atsushi Yokoyama Ignaas Verpoest Zen-ichiro Maekawa 《Composite Structures》1995,32(1-4):133-139
This study deals with the impact property and damage tolerance of matrix hybrid composite laminates with different laminate constitution. The matrix hybrid composite laminates consisted of the laminae with a conventional epoxy resin and the laminae with a flexible epoxy resin modified from the conventional resin to avoid the interlaminar delamination. The impact energy absorption ratio greatly depended on the matrix resin placed at the impact face. The energy absorption was almost constant if the conventional resin was placed at the impact surface layer, while it increased exponentially with the increasing fraction of the flexible resin if the flexible resin was placed at the impact face. The impact energy was absorbed by the damage development and propagation in the laminate with conventional resin laminae as the impacted face, while it was absorbed by both the recoverable deformation of the flexible resin and the damage propagation in the laminate with flexible resin laminae as the impacted face. 相似文献
18.
Xiaojun Hu Hiroyuki Matsuura Fumitaka Tsukihashi 《Metallurgical and Materials Transactions B》2006,37(3):395-401
The interfacial reaction between CO2-CO gas and molten iron oxide containing P2O5 was investigated by the 13CO2-CO isotope exchange technique at 1773 K with CO2/CO=1.0. The apparent rate constant rapidly decreased with the addition of P2O5 up to 2.86 mol pct PO2.5 and the Fe3+/Fe2+ ratio kept constant at approximately 0.2. By the classic site blockage model, in which the reaction only occurs on the vacant
sites, and the modified site blockage model, in which the reaction occurs on the vacant sites and the sites occupied by phosphorus
simultaneously, the effect of the addition of P2O5 was analyzed and the reaction mechanism of CO2 dissociation was discussed. It may be concluded that the dissociation of the adsorbed CO2 molecule is reasonable as a rate-determining step and that the effect of phosphorus on the interfacial reaction is caused
by the decrease in the number of active sites with the increase of phosphorus content as a surface active element in molten
iron oxide. 相似文献
19.
The effect of Zr on reduction of hardness and microstructure in an FS weld of equal channel angular-pressed Al alloy was investigated. Zr addition to Al suppressed dynamic recovery in the thermomechanically affected zone and enabled retention of the high hardness of the ECA-pressed material throughout the weld. 相似文献